IB Biology HL Water & Its Properties Paper 1 & 2 ~12 min read

Water’s Physical & Chemical Properties

Water sticks to things, dissolves almost everything, warms up slowly and holds objects afloat. These sound like four unrelated facts. They are really one fact — hydrogen bonding — showing up in four different ways.

📘 What you need to know

Cohesion

Hydrogen bonds between water molecules pull them towards each other. That attraction between molecules of the same substance is called cohesion.

Cohesion Water molecules are attracted to other water molecules by hydrogen bonds

Two consequences matter for the exam:

Adhesion

Water is also attracted to other substances, as long as those substances are polar or charged. That is adhesion. Cellulose, which makes up plant cell walls, is polar — so water sticks to it well.

Adhesion Water molecules are attracted to other polar or charged materials
Cohesion and adhesion inside a xylem vessel The whole column of water is pulled upwards towards the leaves ADHESION water sticks to the cellulose cell wall COHESION water sticks to other water molecules CELL WALL Cohesion keeps the column together. Adhesion keeps it against the wall. Together they let water flow through the plant as one continuous stream.
Hydrogen bonding produces both forces, which is why the column of water does not break as it is pulled up a tall tree.
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Memory trick: CO and AD

COhesion = water sticking to each other (CO- means together, like co-worker).
ADhesion = water sticking to additional materials.

Water as a solvent

Because water is polar, it can surround and pull apart any particle that also carries charge. Biological molecules fall into two groups depending on whether water can do this:

Hydrophobic molecules end up clustered together in groups. This is not because they attract each other — it is because the water molecules around them hydrogen bond to each other instead, pushing the non-polar molecules out of the way. This is called a hydrophobic interaction.

Since most biological molecules are hydrophilic and can be dissolved, water is called the universal solvent.

Why water dissolves some things and not others Na+ δ− oxygen faces the positive ion Cl− δ+ hydrogen faces the negative ionHYDROPHILIC — dissolves HYDROPHILIC — dissolves non-polar molecule — no charge, no hydrogen bonds, HYDROPHOBIC
Water pulls ionic and polar substances apart by surrounding each particle. A non-polar molecule has nothing for water to grip, so it stays undissolved.

Solubility of different biological molecules

GroupExamplesWhat it means for the organism
Highly solubleSodium chloride, urea, glucose, amino acidsEasily transported in solution around the body. Even amino acids with hydrophobic R groups are soluble enough to travel in water
Sparingly (less) solubleOxygenDissolves just enough in oceans, rivers and lakes for aquatic animals to breathe, but needs haemoglobin to carry useful amounts in blood. Oxygen is less soluble at 37 °C than at 20 °C
InsolubleFats, phospholipid tailsBeing hydrophobic is the whole point — phospholipid hydrocarbon tails form the hydrophobic core of the cell membrane
Enzymes need water too. Most enzymes need water to hold their shape and stay stable, which lets them catalyse reactions in aqueous solution. Hydrogen bonds also help the substrate bind into the active site to form the enzyme–substrate complex.

Specific heat capacity

Definition The energy needed to raise the temperature of 1 kg of a substance by 1 °C

Water’s specific heat capacity is 4200 J/kg/°C, compared with about 1000 J/kg/°C for air. So it takes a lot of energy to warm water up, and water releases a lot of energy as it cools down.

The reason is the hydrogen bonds. A large amount of the thermal energy going in is used to break hydrogen bonds rather than to speed the molecules up, so the temperature does not rise much.

Why this matters to living things:

Ice floats. Solid water is less dense than liquid water, so ice forms on the surface rather than the bottom. That gives seals a habitat on top of the floating ice sheets and underneath them, and it stops lakes and seas freezing solid.

Thermal conductivity

Definition The ability of a substance to conduct heat

Water conducts heat almost 30 times better than air. Flip that around and it gives you the useful conclusion: air is a very good insulator, which is exactly why animals in cold climates trap air.

Ice floats, and that keeps the water below liveable COLD AIR low thermal conductivity — a good insulator FLOATING ICE less dense than liquid water, so it sits on top LIQUID WATER — STABLE AND WARMER high specific heat capacity, so the temperature changes slowly habitat for the ringed seal and other Arctic species thermal energy rises but is trapped by the ice layer
Two properties working together: low density of ice puts the lid on, and low thermal conductivity of ice keeps the heat in.

Buoyancy

Definition The ability of an object to float in water

Water is dense, so it pushes objects upwards strongly. Air barely does this at all. Depending on the animal, that upward push is either a problem to solve or an advantage to use.

Viscosity

Definition The resistance of a fluid to flow

Water is much more viscous than air, so moving through water takes far more effort than moving through air.

Water vs air — the comparison the IB asks for

PropertyWaterAirAdaptation it explains
Specific heat capacityHigh (4200 J/kg/°C)Lower (about 1000 J/kg/°C)Stable sea temperatures let the ringed seal survive all year
Thermal conductivityAbout 30× higherLow — a good insulatorLoon traps air in its feathers; seal uses blubber
BuoyancyHighVery lowLoon has solid bones to dive; seal’s blubber aids floating
ViscosityMuch higherLowStreamlined bodies, flippers and webbed feet for water; easy flight through air
You may use either the common name or the scientific name for these two organisms in an exam. What you cannot do is answer a “compare water and air” question without mentioning an actual adaptation — the marks are usually for the link, not for the property.

Worked examples

WE 1

Explain how water moves up the xylem of a tall tree

Explain how the properties of water allow it to move from the roots to the leaves of a tall tree. (3 marks)

Point 1: name the force between water molecules Hydrogen bonds between water molecules cause cohesion, so the molecules stick to each other. Point 2: explain the continuous column This holds the water together as an unbroken column that can be pulled upwards under tension without breaking. Point 3: bring in the vessel wall Adhesion between water and the polar cellulose of the xylem wall helps hold the column in place and supports capillary action. Cohesion holds the column together; adhesion holds it to the wall Use both words. Answers that only say “cohesion” usually cap at 2 marks.
WE 2

Explain why glucose dissolves in water but a fat does not

Explain, in terms of molecular structure, why glucose is soluble in water but a lipid is not. (3 marks)

Point 1: glucose is polar Glucose has hydroxyl (–OH) groups, which are polar, so it can form hydrogen bonds with water. Point 2: water surrounds it Water molecules surround each glucose molecule and separate them, so glucose is hydrophilic and dissolves. Point 3: fats are non-polar A lipid’s hydrocarbon chains carry no charge, so no hydrogen bonds form with water. It is hydrophobic and stays undissolved. Hydrogen bonding with water is the deciding factor, and that needs charge “It’s polar so it dissolves” is only half an answer — say why polarity matters: hydrogen bonds.
WE 3

Compare the thermal properties of water and air

Using named examples, compare the thermal conductivity of water and air and explain how animals are adapted to this difference. (4 marks)

Point 1: state the comparison Water conducts heat about 30 times better than air, so animals lose body heat far faster in water than in air. Point 2: air is therefore an insulator The black-throated loon (Gavia arctica) traps a layer of air in its feathers to reduce heat loss. Point 3: the alternative solution The ringed seal (Pusa hispida) uses a thick layer of blubber instead of trapped air. Point 4: add the ice point Ice conducts heat poorly, so a surface ice layer traps thermal energy and keeps the water underneath warmer. High conductivity in water → animals need insulation, from air or from fat Name at least one organism. “Compare” questions expect a clear difference plus a consequence.

💡 Exam tips

⚠ Common mistakes

Up next: Origin of Water on Earth — how water arrived on a planet that was once far too hot for it, and how astronomers hunt for it on planets orbiting other stars.

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