IB Chemistry SL Topic 2 — Metallic Bonding Paper 1 & 2 Structure & properties ~11 min read

Metallic Properties and Uses

Metals conduct, bend, shine and melt at high temperatures. Every one of those properties comes out of the same picture — positive ions in a sea of delocalised electrons. Learn to argue from that model and you can explain any of them.

📚 What you need to know

Malleability and ductility

Malleable means it can be hammered into sheets. Ductile means it can be pulled into wires. Both come from the same thing: the metal ions are arranged in layers, and a force can make one layer slide over another.

The key point is what happens during the slide. The delocalised electrons are not attached to any particular ion, so they simply move along with them. The attraction between ions and electrons is never broken, so the metal changes shape without falling apart.

WHY METALS BEND INSTEAD OF SHATTERINGBEFORE++++++++++++++++++++AFTER A FORCE IS APPLIED++++++++++++++++++++forcethe layers slide, but the electrons flow with them so the attraction is never lostnothing like ionic solids, where sliding brings like charges together and the crystal cracks
The top two layers have shifted to the right. Because every ion has the same charge and the electrons travel with them, nothing repels and nothing breaks.
Compare this with an ionic solid. There, sliding a layer brings like charges next to each other, they repel, and the crystal shatters. In a metal every ion has the same charge and the electron glue moves with them — so metals bend where ionic solids crack. That contrast is a favourite exam question.

Electrical conductivity

To conduct electricity you need charged particles that can move. A metal has them ready-made: the delocalised electrons. Connect a metal to a power supply and those electrons are repelled from the negative terminal and drift towards the positive terminal, carrying charge through the metal.

This is why metals are so different from ionic compounds. An ionic solid has to be melted or dissolved before its ions can move. A metal conducts as a solid, because nothing has to break for the electrons to travel.

HOW A METAL CONDUCTS ELECTRICITY++++++++++++++++the delocalised electrons drift towards the positive terminalthey can do this in the solid as well as the liquid — no melting needed
The ions stay put; only the electrons move. That is why a solid metal conducts while a solid ionic compound cannot.

💡 Conductivity increases across a period

Thermal conductivity

Metals also carry heat extremely well, and there are two reasons working together:

The second mechanism is much faster than the first, which is why metals feel cold to touch — they are pulling heat out of your hand very efficiently.

Melting point, strength and hardness

Melting a metal means overcoming the attraction between the ions and the electron sea. That attraction is strong and acts in all directions, so a lot of energy is needed — hence the high melting and boiling points.

The same attraction plus the close packing of the ions is what makes metals strong and hard. And because the attraction gets stronger with more delocalised electrons, higher ionic charge and smaller ions, the melting point rises across a period. That trend is the subject of the next set of notes.

The other properties worth knowing

PropertyWhat it meansWhy
LustreShiny when polishedDelocalised electrons reflect light
SonorityRings when struckThe lattice vibrates without breaking
DensityUsually highIons are packed very closely together
Strength-to-weight ratioStrong for its massMatters for aircraft and vehicles
Corrosion resistanceResists reacting with air or waterDepends on reactivity and any oxide layer
ToxicityWhether it is safe for contactCritical for food, water pipes and implants

Choosing a metal for a job

Exam questions on uses are really “match the property to the requirement” questions. Look at what the object has to do, then pick the properties that matter:

UseMetalProperties that matter
Electrical wiringCopperExcellent electrical conductor; ductile so it can be drawn into thin wire
Food and drink cansAluminiumNon-toxic, resists corrosion by acidic foods, low density, malleable
CutleryStainless steelStrong, hard, resists corrosion, non-toxic
SaucepansAluminium or copper baseHigh thermal conductivity, high melting point
Aircraft bodiesAluminium alloysHigh strength-to-weight ratio, corrosion resistant
WORKED EXAMPLE

Explain why magnesium can be bent into shape but magnesium oxide shatters when hit.

Magnesium is metallic — layers of Mg²⁺ ions in a sea of electrons When layers slide, the delocalised electrons move with them. the attraction is maintained, so it bends MgO is ionic — alternating Mg²⁺ and O²⁻ ions Sliding a layer brings ions of the SAME charge next to each other. strong repulsion splits the crystal → it shatters
WORKED EXAMPLE

Suggest why copper rather than aluminium is used for household electrical wiring, even though aluminium is cheaper and lighter.

Copper is a better electrical conductor than aluminium Less energy is wasted as heat in the wires. Copper is very ductile, so it can be drawn into thin flexible wire Copper also resists corrosion well the better conductivity outweighs the extra cost and mass indoors Aluminium IS used for overhead power lines, where low mass matters more.

⚠️ Common mix-up

Up next: s-Block and p-Block Elements — why not all metallic bonds are equally strong, and how melting points change across a period and down a group.

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