IB Chemistry SL Topic 8 — Concluding and Evaluating Internal assessment Practical skill ~12 min read

Drawing Conclusions

A conclusion is short. That is the part students find hardest to believe, so they pad it out with everything they wish had gone better. All it has to do is answer the question you asked at the start, using the numbers you have in front of you.

📚 What you need to know

Answer the question you actually asked

Go back and read your research question, word for word. Your first sentence should read like a reply to it. If your question named a range, a chemical and a measurement, your conclusion names the same things.

Weak conclusions drift into general chemistry: “this shows that concentration affects the rate of reaction.” True, and known since before you were born. A conclusion is about your experiment and your numbers.

FOUR LAYERS, IN THIS ORDERa whole conclusion is usually one short paragraph1234THE DIRECT ANSWERone sentence that replies to the research question you wroteTHE EVIDENCEyour processed value, with its uncertainty, or the gradient of your graphTHE CHEMISTRYthe principle the result is consistent with, named in one clauseTHE COMPARISONthe literature value, where it came from, and the percentage errornot here: new explanations, improvements, or apologieseverything in a conclusion has already appeared earlier in the reportif a sentence is new information, it is in the wrong section
Layer four is the one most students leave out, and it is the one that lets you say anything at all about accuracy.

Say what happened to your hypothesis

You made a prediction at the start with a reason attached. Now say straight out whether the data backed it up. Do not leave the reader to work it out from the graph.

And if the data went against your prediction, write that down plainly. A hypothesis that turns out to be wrong is a result, not a failure, and pretending otherwise is far more damaging than being wrong was. What you must not do is quietly change the hypothesis afterwards so it matches what happened.

There is a middle case worth knowing. Sometimes the data neither supports nor refutes the prediction, because the scatter is too big to tell. Saying so — “the trend is in the predicted direction but the spread of results is too large to claim it with confidence” — is a much stronger answer than forcing a conclusion the data cannot carry.

Compare with the accepted value

You can only comment on accuracy if there is something to be accurate against. So find a literature value, say where you found it, and turn “quite close” into a number.

Percentage error % error = |experimental − literature| ÷ literature × 100

Cite the source in the same sentence: the IB data booklet, a named textbook, a chemical database. “I looked it up” is not a citation, and an assessor cannot check it.

The comparison that separates a good IA from an average one

Here is the move most students never make. You have two percentages by this point: the percentage error, which says how far you are from the accepted value, and the percentage uncertainty, which says how far off you could be just because of your equipment. Put them next to each other.

DOES YOUR RANGE REACH THE ACCEPTED VALUE?two students, the same experiment, two very different sentencesliterature −57.3student A: −57 ± 2 kJ mol⁻¹the accepted value falls inside the range−50−52−54−56−58−60ΔH / kJ mol⁻¹student B: −52.3 ± 2 kJ mol⁻¹the accepted value is nowhere near itstudent A agrees with the literature within experimental limitsstudent B has a gap that equipment alone cannot explain
Both students had the same 3.2% uncertainty. What differs is the gap: 0.5% for A, 8.7% for B. That gap is the whole story.
What you findWhat it meansHow to say it
Percentage error is smaller than your percentage uncertaintyThe literature value sits inside your range, so the gap could be explained by your equipment alone“the result agrees with the accepted value within experimental uncertainty”
Percentage error is much larger than your percentage uncertaintyYour equipment cannot account for the gap, so something in the method is pushing every result the same way“the difference is too large to be random, which points to a systematic error”
They are roughly the same sizeBorderline. Your result is consistent, but only just“the result is consistent with the accepted value, though the margin is small”
Notice what the second row buys you. You have not just admitted a problem — you have proved one exists, using two numbers you already worked out. That gives your evaluation something real to chase, instead of a list of things that might in principle have gone wrong.

What does not belong in a conclusion

WORKED EXAMPLE

A student writes: “In conclusion the experiment went well and my answer was quite close to the real value, which proves that concentration affects the rate of reaction. Next time I would use better equipment.” Identify four faults.

Fault 1: no number anywhere There is no result, no uncertainty and no literature value, so nothing here can be checked. Fault 2: “quite close” is not a comparison Accuracy is quantified with a percentage error, not described with an adjective. Fault 3: it answers a textbook question, not this one “Concentration affects rate” was already known. The research question asked about a specific reaction over a specific range. Fault 4: the improvement is in the wrong section And “better equipment” is too vague to be an improvement anywhere. a better opening sentence “The initial rate of reaction was found to be directly proportional to the concentration of hydrochloric acid over the range 0.50 to 2.50 mol dm−3, with a gradient of 0.00999 dm3 mol−1 s−1.”
WORKED EXAMPLE

Student A found the enthalpy of neutralisation of HCl with NaOH to be −57 ± 2 kJ mol−1, a percentage uncertainty of 3.2%. The literature value is −57.3 kJ mol−1. Write the accuracy part of the conclusion.

Work out the percentage error |57 − 57.3| ÷ 57.3 × 100 = 0.52% Compare the two percentages The error of 0.5% is far smaller than the uncertainty of 3.2%, so the difference is well within what the equipment alone could produce. Check the range directly −57 ± 2 gives −55 to −59, which contains −57.3 the result agrees with the accepted value Written out “The experimental value of −57 ± 2 kJ mol−1 gives a percentage error of 0.5% against the accepted value of −57.3 kJ mol−1. Since this is much smaller than the propagated uncertainty of 3.2%, the result is consistent with the literature value within experimental limits.”
WORKED EXAMPLE

Student B ran the same experiment and obtained −52.3 ± 2 kJ mol−1, also with a 3.2% uncertainty. Write their accuracy paragraph and say what it tells them.

Percentage error (57.3 − 52.3) ÷ 57.3 × 100 = 8.7% Compare 8.7% against an uncertainty of 3.2%. The gap is nearly three times bigger than the equipment can account for. Check the range −52.3 ± 2 gives −50.3 to −54.3, and −57.3 is outside it a systematic error is present Which direction? Every value was less exothermic than it should be, which is exactly what heat escaping the cup would do. The conclusion states this; the evaluation is where it gets chased down. Note that B’s results could still be beautifully precise. Precision and accuracy are separate questions, and this is a result that answers them differently.

💡 Exam tip

⚠️ Common mix-up

Up next: Evaluating — you have just shown, with two percentages, that something in the method was pushing your results one way. The next page is about finding out what, and saying what you would do about it.

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